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10.33826/ijmras/v05i01.3

ENERGY EFFICIENT NANOCELLULOSE SHEETS FOR PRODUCT APPLICATION

Abstract

Synthetic polymers and plastics which are currently used as barrier materials in the packaging industry are neither renewable nor biodegradable, creating a serious threat to the ecosystem. Nano cellulose which is obtained by breaking down cellulose fibers into nano-scale dimensions has unique properties with the potential to dramatically impact many commercial markets including packaging. This research investigates the refining of cellulose fiber to produce sustainable nano cellulose using a laboratory PFI mill and industrial Disc refiner. Refined pulp was made into nano cellulose sheets using standard laboratory paper making technique through vacuum filtration. The tensile index and sheet density for PFI mill refined BEK and Disc refined NBSK showed approximately five times and two times improvement over unrefined BEK and NBSK pulp respectively highlighting the role of refining in improving the mechanical structure of nano cellulose sheets. This strength enhancement comes at a cost of 17417 kWh/t specific refining energy in lab-scale PFI mill refining and 3346.3 kWh/t specific refining energy in industrial-scale Disc refining. Fines generation as a result of refining decreased the porosity by 37.972% and 48.939% in Disc refined NBSK and PFI mill refined BEK respectively which improved the water vapor and oxygen permeability. Refining decreased the water vapor permeability by approximately ten times for both BEK and NBSK making them very comparable with synthetic polymers such as polyethylene (PE). The lowest value of oxygen permeability achieved with PFI mill refined BEK and Disc refined NBSK was 0.533±0.098 and 0.762±0.03 (cc.µm)/(m2.day.kPa) which is very competitive with that of polymers used in plastics. Additionally, the surface roughness decreased by 77.05% and 52.8% for PFI mill refined BEK and Disc refined NBSK respectively which promises refining as an excellent tool to produce smooth nano cellulose sheets for printed electronics applications.

Keywords
  • Synthetic polymer,
  • ; Nanocellulose,
  • packaging industry,
  • laboratory PFI mill,
  • high aspect ratio
References
  • Abdollahi, Mehdi, Mehdi Alboofetileh, Rabi Behrooz, Masoud Rezaei, and Reza Miraki. 2013. 'Reducing water sensitivity of alginate
  • bio-nano composite film using cellulose nanoparticles', International journal of biological macromolecules, 54: 166-73.
  • Agate, Sachin, Michael Joyce, Lucian Lucia, and Lokendra Pal. 2018. 'Cellulose and nano-cellulose-based flexible-hybrid printed
  • electronics and conductive composites–a review', Carbohydrate polymers, 198: 249-60.
  • Ahmadzadeh, Safoura, Ali Nasirpour, Javad Keramat, Nasser Hamdami, Tayebeh Behzad, and Stephane Desobry. 2015.
  • 'Nanoporous cellulose nanocomposite foams as high insulated food packaging materials', Colloids and Surfaces A:
  • Physicochemical and Engineering Aspects, 468: 201-10.
  • Alves, JS, KC Dos Reis, EGT Menezes, FV Pereira, and J Pereira. 2015. 'Effect of cellulose nanocrystals and gelatin in corn starch
  • plasticized films', Carbohydrate polymers, 115: 215-22.
  • Ang, Shaun, Victoria Haritos, and Warren Batchelor. 2019. 'Effect of refining and homogenization on nano-cellulose fiber
  • development, sheet strength, and energy consumption', Cellulose, 26: 4767-86.
  • ASTM, F. 1927. "07. Standard Test Method for Determination of Oxygen Gas Transmission Rate, Permeability, and Permeance at
  • Controlled Relative Humidity Through Barrier Materials Using a Coulometric Detector. American National Standards Institute.
  • Aug. 2007." In.
  • Aulin, Christian, Mikael Gällstedt, and Tom Lindström. 2010. 'Oxygen and oil barrier properties of micro-fibrillated cellulose films
  • and coatings', Cellulose, 17: 559-74.
  • Aulin, Christian, German Salazar-Alvarez, and Tom Lindström. 2012. 'High strength, flexible and transparent nanofibrillated
  • cellulose–nano clay biohybrid films with tunable oxygen and water vapor permeability, Nanoscale, 4: 6622-28.
  • Bhunia, Kanishka, Shyam S Sablani, Juming Tang, and Barbara Rasco. 2013. 'Migration of chemical compounds from packaging
  • polymers during the microwave, conventional heat treatment, and storage', Comprehensive Reviews in Food Science and Food
  • Safety, 12: 523-45.
  • El Miri, Nassima, Karima Abdelouahdi, Abdellatif Barakat, Mohamed Zahouily, Aziz Fihri, Abderrahim Solhy, and Mounir El Achaby.
  • 'Bio-nanocomposite films reinforced with cellulose nanocrystals: Rheology of film-forming solutions, transparency, water
  • vapor barrier and tensile properties of films', Carbohydrate polymers, 129: 156-67.
  • Fernando, Dinesh, Dino Muhić, Per Engstrand, and Geoffrey Daniel. 2011. 'Fundamental understanding of pulp property
  • development under different thermomechanical pulp refining conditions as observed by a new Simons’ staining method and SEM
  • observation of the ultrastructure of fiber surfaces', Holzforschung, 65: 777-786.
  • Ferrer, Ana, Lokendra Pal, and Martin Hubbe. 2017. 'Nanocellulose in packaging: Advances in barrier layer technologies',
  • Industrial Crops and Products, 95: 574-82.
  • Fukuzumi, Hayaka, Tsuguyuki Saito, Tadahisa Iwata, Yoshiaki Kumamoto, and Akira Isogai. 2009. 'Transparent and high gas
  • barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation', Biomacromolecules, 10: 162-65.
  • Garusinghe, Uthpala M, Swambabu Varanasi, Vikram S Raghuwanshi, Gil Garnier, and Warren Batchelor. 2018. 'Nanocellulose-
  • montmorillonite composites of low water vapor permeability, Colloids and Surfaces A: Physicochemical and Engineering Aspects,
  • : 233-41.
  • Giesche, Herbert. 2006. 'Mercury porosimetry: a general (practical) overview', Particle & particle systems characterization, 23: 9-19
  • González, I, F Vilaseca, M Alcalá, MA Pèlach, S Boufi, and P Mutjé. 2013. 'Effect of the combination of bio beating and NFC on the
  • physicomechanical properties of paper', Cellulose, 20: 1425-35.
  • Ho, Thao TT, Tanja Zimmermann, Steffen Ohr, and Walter R Caseri. 2012. 'Composites of cationic nano fibrillated cellulose and
  • layered silicates: water vapor barrier and mechanical properties, ACS applied materials & interfaces, 4: 4832-40.
  • Hoeng, Fanny, Aurore Denneulin, and Julien Bras. 2016. 'Use of nano-cellulose in printed electronics: a review', Nanoscale, 8:
  • - 54.
  • Honorato, Camila, Vinay Kumar, Jun Liu, Hanna Koivula, Chunlin Xu, and Martti Toivakka. 2015. 'Transparent nano-cellulose-
  • pigment composite films', Journal of materials science, 50: 7343-52.
  • Hubbe, Martin A, Ana Ferrer, Preeti Tyagi, Yuanyuan Yin, Carlos Salas, Lokendra Pal, and Orlando J Rojas. 2017. 'Nanocellulose in
  • thin films, coatings, and plies for packaging applications: A review', BioResources, 12: 2143-233.
  • Hyll, Kari. 2015. 'Size and shape characterization of fines and fillers-a review', Nordic Pulp & Paper Research Journal, 30: 466-87.
  • Impee, P. 2005. 'Recycling of plastics', The impee project university of Cambridge.
  • Isogai, Akira. 2013. 'Wood nanocelluloses: fundamentals and applications as new bio-based nanomaterials', Journal of wood
  • science, 59: 449-59.
  • Johansson, Caisa, Julien Bras, Iñaki Mondragon, Petronela Nechita, David Plackett, Peter Simon, Diana Gregor Svetec, Sanna
  • Virtanen, Marco Giacinti Baschetti, and Chris Breen. 2012. 'Renewable fibers and bio-based materials for packaging applications–a
  • review of recent developments, BioResources, 7: 2506-52.
  • Kim, Joo-Hyung, Bong Sup Shim, Heung Soo Kim, Young-Jun Lee, Seung-Ki Min, Daseul Jang, Zafar Abas, and Jaehwan Kim. 2015.
  • 'Review of nano-cellulose for sustainable future materials', International Journal of Precision Engineering and Manufacturing-
  • Green Technology, 2: 197-213.
  • Kumar, Saurabh. 2012. 'Deinking pulp fractionation: characterization and separation of fines by screening'.
  • Kuswandi, B. 2017. 'Environmental friendly food nano packaging, Environmental Chemistry Letters, 15: 205-21.
  • Lange, J, and Yves Wyser. 2003. 'Recent innovations in barrier technologies for plastic packaging—a review', Packaging
  • Technology and Science: An International Journal, 16: 149-58.
  • Lavoine, Nathalie, Isabelle Desloges, Alain Dufresne, and Julien Bras. 2012. 'Microfibrillated cellulose–Its barrier properties and
  • applications in cellulosic materials: A review, Carbohydrate polymers, 90: 735-64.
  • Li, Fei, Erika Mascheroni, and Luciano Piergiovanni. 2015. 'The potential of nano-cellulose in the packaging field: a review',
  • Packaging Technology and Science, 28: 475-508.
  • Li, Qingqing, Sean McGinnis, Cutter Sydnor, Anthony Wong, and Scott Renneckar. 2013. 'Nanocellulose life cycle assessment', ACS
  • Sustainable Chemistry & Engineering, 1: 919-28.
  • Mohamed, Radin Maya Saphira Radin, Gazala Sanusi Misbah, Anwaruddin Ahmed Wurochekke, and Amir Hashim bin Mohd
  • Kassim. 2014. 'Energy recovery from polyethylene terephthalate (PET) recycling process', GSTF Journal of Engineering
  • Technology (JET), 2: 1-6
  • Nair, Sandeep S, JY Zhu, Yulin Deng, and Arthur J Ragauskas. 2014. 'High-performance green barriers based on nano cellulose,
  • Sustainable Chemical Processes, 2: 23.
  • Nakagaito, Antonio Norio, and Hiroyuki Yano. 2005. 'Novel high-strength biocomposites based on micro-fibrillated cellulose
  • having nano-order-unit web-like network structure', Applied Physics A, 80: 155-59.
  • Nugroho, Dimas Dwi Prasetyo. 2012. 'Low consistency refining of mixtures of softwood & hardwood bleached kraft pulp: effects of
  • refining power', Asian Institute of Technology.
  • Okada, Akane, and Arimitsu Usuki. 2006. 'Twenty years of polymer‐clay nanocomposites', Macromolecular Materials and
  • Engineering, 291: 1449-76.
  • Osong, Sinke H, Sven Norgren, and Per Engstrand. 2016. 'Processing of wood-based micro-fibrillated cellulose and nano-fibrillated
  • cellulose, and applications relating to papermaking: a review', Cellulose, 23: 93-123.
  • Österberg, Monika, Jari Vartiainen, Jessica Lucenius, Ulla Hippi, Jukka Seppälä, Ritva Serimaa, and Janne Laine. 2013. 'A fast
  • method
  • to produce strong NFC films as a platform for barrier and functional materials, ACS applied materials & interfaces, 5: 4640-47.
  • Paralikar, Shweta A, John Simonsen, and John Lombardi. 2008. 'Poly (vinyl alcohol)/cellulose nanocrystal barrier membranes',
  • Journal of Membrane Science, 320: 248-58.
  • Piccinno, Fabiano, Roland Hischier, Stefan Seeger, and Claudia Som. 2018. 'Predicting the environmental impact of a future
  • nano-cellulose production at industrial scale: Application of the life cycle assessment scale-up framework', Journal of Cleaner
  • Production, 174: 283-95
  • Rhim, Jong-Whan, and Perry KW Ng. 2007. 'Natural biopolymer-based nanocomposite films for packaging applications, Critical
  • reviews in food science and nutrition, 47: 411-33.
  • Rodionova, Galina, Marianne Lenes, Øyvind Eriksen, and Øyvind Gregersen. 2011. 'Surface chemical modification of
  • micro fibrillated cellulose: improvement of barrier properties for packaging applications', Cellulose, 18: 127-34.
  • Sehaqui, Houssine, Andong Liu, Qi Zhou, and Lars A Berglund. 2010. 'Fast preparation procedure for large, flat cellulose and
  • cellulose/inorganic nano paper structures', Biomacromolecules, 11: 2195-98.
  • Sehaqui, Houssine, Seira Morimune, Takashi Nishino, and Lars A Berglund. 2012. 'Stretchable and strong cellulose nanopaper
  • structures based on polymer-coated nanofiber networks: An alternative to nonwoven porous membranes from electrospinning',
  • Biomacromolecules, 13: 3661-67.
  • Seth, RS. 2003. 'measurement and significance of fines', Pulp & Paper Canada.
  • Shanmugam, Kirubanandan, Humayun Nadeem, Christine Browne, Gil Garnier, and Warren Batchelor. 2020. 'Engineering surface
  • roughness of nano-cellulose film via spraying to produce smooth substrates', Colloids and Surfaces A: Physicochemical and
  • Engineering Aspects, 589: 124396
  • Sharma, Sudhir, Xiaodan Zhang, Sandeep S Nair, Arthur Ragauskas, Junyong Zhu, and Yulin Deng. 2014. 'Thermally enhanced
  • high- performance cellulose nanofibril barrier membranes', RSC Advances, 4: 45136-42.
  • Shimizu, Michiko, Tsuguyuki Saito, and Akira Isogai. 2016. 'Water-resistant and high oxygen-barrier nano-cellulose films with
  • interfibrillar cross-linkages formed through multivalent metal ions, Journal of Membrane Science, 500: 1-7.
  • Silvério, Hudson Alves, Wilson Pires Flauzino Neto, and Daniel Pasquini. 2013. 'Effect of incorporating cellulose nanocrystals from
  • corncob on the tensile, thermal, and barrier properties of poly (vinyl alcohol) nanocomposites, Journal of Nanomaterials, 2013.
  • Sim, Kyujeong, and Hye Jung Youn. 2016. 'Preparation of porous sheets with high mechanical strength by the addition of cellulose
  • nanofibrils', Cellulose, 23: 1383-92.
  • Siró, István, and David Plackett. 2010. 'micro fibrillated cellulose and new nanocomposite materials: a review', Cellulose, 17: 459-
  • Stankovská, Monika, Juraj Gigac, Mária Fišerová, and Elena Opálená. 2019. 'RELATIONSHIP BETWEEN STRUCTURAL PARAMETERS
  • AND WATER ABSORPTION OF BLEACHED SOFTWOOD AND HARDWOOD KRAFT PULPS', WOOD RESEARCH, 64: 261-72.
  • Steven, Matthew D, and Joseph H Hotchkiss. 2002. 'Comparison of flat film to total package water vapour transmission rates for
  • several commercial food wraps', Packaging Technology and Science: An International Journal, 15: 17-27.
  • Strategy, Plastic. 2018. 'A European strategy for plastics in a circular economy, Communication from the Commission to the
  • European Parliament, the Council, the European Economic, and Social Committee, and the Committee of the Regions. Brussels.
  • Thao Ho, Thi Thu, Tanja Zimmermann, Walter Remo Caseri, and Paul Smith. 2013. 'Liquid ammonia treatment of (cationic) nano
  • fibrillated cellulose/vermiculite composites', Journal of Polymer Science Part B: Polymer Physics, 51: 638-48.
  • Tharanathan, RN. 2003. 'Biodegradable films and composite coatings: past, present and future', Trends in food science &
  • technology, 14: 71-78.
  • Tingaut, Philippe, Tanja Zimmermann, and Francisco Lopez-Suevos. 2010. 'Synthesis and characterization of bio-nano composites
  • with tunable properties from poly (lactic acid) and acetylated micro fibrillated cellulose', Biomacromolecules, 11: 454-64.
  • Varanasi, Swambabu, and Warren J Batchelor. 2013. 'Rapid preparation of cellulose nanofibre sheet', Cellulose, 20: 211-15.
  • Watkins, Emma, and Jean-Pierre Schweitzer. 2018. 'Moving towards a circular economy for plastics in the EU by 2030.' in, Think
  • Brussels: Institute for European Environmental Policy (IEEP).
  • Youssef, Ahmed M, Magda Ali El-Samahy, and Mona H Abdel Rehim. 2012. 'Preparation of conductive paper composites based on
  • natural cellulosic fibers for packaging applications', Carbohydrate polymers, 89: 1027-32.
  • Zeng, Xiling, Shiyu Fu, Elias Retulainen, and Sabine Heinemann. 2012. 'Fibre deformations induced by different mechanical
  • treatments and their effect on zero-span strength', Nordic Pulp & Paper Research Journal, 27: 335-42.
  • Zhang, Liyuan, Warren Batchelor, Swambabu Varanasi, Takuya Tsuzuki, and Xungai Wang. 2012. 'Effect of cellulose nanofiber
  • dimensions on sheet forming through filtration, Cellulose, 19: 561-74.

Authors

  • Wriju Kargupta
    Affiliation:- Bioresource Processing Research Institute of Australia, Chemical Engineering Department, Monash University, Clayton,
  • Joanne Tanner
    Affiliation:- Bioresource Processing Research Institute of Australia, Chemical Engineering Department, Monash University, Clayton, Australia.
  • Warren Batchelor
    Affiliation:- Bioresource Processing Research Institute of Australia, Chemical Engineering Department, Monash University, Clayton, Australia.

How to Cite

Kargupta, W., Tanner, J. ., & Batchelor, W. . (2022). ENERGY EFFICIENT NANOCELLULOSE SHEETS FOR PRODUCT APPLICATION. International Journal of Multidisciplinary Research and Studies, 5(01), 01–23. https://doi.org/10.33826/ijmras/v05i01.3

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